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Diffusion couple experiments were carried out with San Carlos olivine (Fo90) and NiFe alloys (Ni100, Ni97Fe3, Ni90Fe10) or other olivine compositions (Fo100, Fo25) in order to determine the dependence on temperature, oxygen fugacity, composition and crystallographic orientation of Ni diffusion coefficient (DNi) in olivine. Experiments at 1 atmosphere total pressure cover a temperature range of 900-1445°C with run durations from 48 to 2155 h at different oxygen fugacities. In an Arrhenius plot the best fit for all data for Fo90 yields an activation energy (ED) of 220 ± 14 kJ/mol and an fO2 dependence of (1/4.25)·Δ log fO2 = Δ log DNi. The relationship between diffusion coefficients along different crystallographic axes at 1200°C is given by D[001] ≈ 6·D[100] ≈ 6·D[010]. DNi depends strongly on the major element (i.e. Fe/Mg) composition of olivine and decreases by about 1 order of magnitude as the olivine composition changes from Fo35 to Fo90. Thus, experimental investigations in Fe-free systems cannot be applied to natural samples. For calculation of residence times or cooling rates the present Ni data yield shorter timescales compared to those obtained using diffusion data published until now.In addition to Ni diffusion coefficients, Fe-Mg, Mn and Ca diffusion data were obtained from some of the same diffusion couples (Fo90-Fo100). It is found that the activation energies, ED[Ni] ≅ ED[Fe-Mg] ≅ ED[Mn] ≤ ED[Ca]. All diffusion coefficients are strongly dependent on the major element composition of olivine. 相似文献
64.
Soil formation and weathering in a permafrost environment of the Swiss Alps: a multi‐parameter and non‐steady‐state approach 下载免费PDF全文
Barbara Zollinger Christine Alewell Christof Kneisel Dagmar Brandová Marta Petrillo Michael Plötze Marcus Christl Markus Egli 《地球表面变化过程与地形》2017,42(5):814-835
Spatially discontinuous permafrost conditions frequently occur in the European Alps. How soils under such conditions have evolved and how they may react to climate warming is largely unknown. This study focuses on the comparison of nearby soils that are characterised by the presence or absence of permafrost (active‐layer thickness: 2–3 m) in the alpine (tundra) and subalpine (forest) range of the Eastern Swiss Alps using a multi‐method (geochemical and mineralogical) approach. Moreover, a new non‐steady‐state concept was applied to determine rates of chemical weathering, soil erosion, soil formation, soil denudation, and soil production. Long‐term chemical weathering rates, soil formation and erosion rates were assessed by using immobile elements, fine‐earth stocks and meteoric 10Be. In addition, the weathering index (K + Ca)/Ti, the amount of Fe‐ and Al‐oxyhydroxides and clay minerals characteristics were considered. All methods indicated that the differences between permafrost‐affected and non‐permafrost‐affected soils were small. Furthermore, the soils did not uniformly differ in their weathering behaviour. A tendency towards less intense weathering in soils that were affected by permafrost was noted: at most sites, weathering rates, the proportion of oxyhydroxides and the weathering stage of clay minerals were lower in permafrost soils. In part, erosion rates were higher at the permafrost sites and accounted for 79–97% of the denudation rates. In general, soil formation rates (8.8–86.7 t/km2/yr) were in the expected range for Alpine soils. Independent of permafrost conditions, it seems that the local microenvironment (particularly vegetation and subsequently soil organic matter) has strongly influenced denudation rates. As the climate has varied since the beginning of soil evolution, the conditions for soil formation and weathering were not stable over time. Soil evolution in high Alpine settings is complex owing to, among others, spatio‐temporal variations of permafrost conditions and thus climate. This makes predictions of future behaviour very difficult. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
65.
Shear-Stress Partitioning in Live Plant Canopies and Modifications to Raupach’s Model 总被引:3,自引:2,他引:1
Benjamin?WalterEmail author Christof?Gromke Michael?Lehning 《Boundary-Layer Meteorology》2012,144(2):217-241
The spatial peak surface shear stress tS¢¢{\tau _S^{\prime\prime}} on the ground beneath vegetation canopies is responsible for the onset of particle entrainment and its precise and accurate prediction is essential when modelling soil, snow or sand erosion. This study investigates shear-stress partitioning, i.e. the fraction of the total fluid stress on the entire canopy that acts directly on the surface, for live vegetation canopies (plant species: Lolium perenne) using measurements in a controlled wind-tunnel environment. Rigid, non-porous wooden blocks instead of the plants were additionally tested for the purpose of comparison since previous wind-tunnel studies used exclusively artificial plant imitations for their experiments on shear-stress partitioning. The drag partitioning model presented by Raupach (Boundary-Layer Meteorol 60:375–395, 1992) and Raupach et al. (J Geophys Res 98:3023–3029, 1993), which allows the prediction of the total shear stress τ on the entire canopy as well as the peak (tS ¢¢/t)1/2{(\tau _S ^{\prime\prime}/\tau )^{1/2}} and the average (tS¢/t)1/2{(\tau _S^{\prime}/\tau )^{1/2}} shear-stress ratios, is tested against measurements to determine the model parameters and the model’s ability to account for shape differences of various roughness elements. It was found that the constant c, needed to determine the total stress τ and which was unspecified to date, can be assumed a value of about c = 0.27. Values for the model parameter m, which accounts for the difference between the spatial surface average tS¢{\tau _S^{\prime}} and the peak tS ¢¢{\tau _S ^{\prime\prime}} shear stress, are difficult to determine because m is a function of the roughness density, the wind velocity and the roughness element shape. A new definition for a parameter a is suggested as a substitute for m. This a parameter is found to be more closely universal and solely a function of the roughness element shape. It is able to predict the peak surface shear stress accurately. Finally, a method is presented to determine the new a parameter for different kinds of roughness elements. 相似文献
66.
GPS Solutions - Precise positioning using the signals of the Global Position System requires correcting the distance between the points of reception of the signal carrier phase and the antenna... 相似文献
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Nanna Andreasen Rebecca Jackson Arka Rudra Henrik Nøhr-Hansen Hamed Sanei Jørgen Bojesen-Koefoed Marit-Solveig Seidenkrantz Christof Pearce Nicolas Thibault Sofia Ribeiro 《Boreas: An International Journal of Quaternary Research》2023,52(4):459-475
The organic matter content of marine sediments is often used to infer past changes in ocean conditions. However, the organic carbon pool preserved in coastal sediments is a complex mixture derived from different sources and may not reflect in situ processes. In this study, we combine taxonomic identification of reworked palynomorphs with pyrolysis organic geochemistry and reflected-light organic petrographic microscopy to investigate the provenance, composition and preservation of organic matter in a marine sediment core retrieved from the NE Greenland shelf. Our study reveals continuous yet variable input of land-derived organic carbon to the marine environment throughout the late Younger Dryas–Holocene, with the highest input of inert carbon in the late Younger Dryas. Although the sediments contain some recent marine palynomorphs, there is no other evidence of fresh marine organic carbon. In contrast, our results indicate that these shelf sediments represent a significant sink of recycled organic carbon. The results of pyrolysis geochemistry revealed that ~90% of the total organic carbon in the sediments is inert. The organic petrography analyses revealed that >70–84% of the organic carbon in the sediment core is terrigenous. Reworked dinoflagellate cysts showed a continuous provenance of Cretaceous land-derived material, most likely from the nearby Clavering Island. Our study points to the importance of constraining the organic matter origin, composition and preservation in marine sediments to achieve more accurate palaeoenvironmental reconstructions based on organic proxies. 相似文献
69.
Charles E. Tilburg Jennie E. Seay T. Dale Bishop Harlan L. Miller III Christof Meile 《Estuarine, Coastal and Shelf Science》2010
Since transport of planktonic larvae is essential to the maintenance and expansion of many marine species, we examined the spatial and temporal distribution of green porcelain crab Petrolisthes armatus (Gibbes, 1850) larvae and the possible underlying physical and behavioral mechanisms using a combination of field observations and numerical modeling. The field study consisted of observations of larval abundance and distribution as well as hydrographic surveys of the Satilla River estuary on the east coast of the USA in August 2006. Larvae were found throughout the water column within the tributaries but primarily at depth in the main river. A numerical model was used to examine the effect of flow and possible larval behavior responsible for the observed distribution and the consequences for larval retention in the estuary. Model results that included downward larval movement are consistent with the field observations, supporting the hypothesis that P. armatus larvae vertically migrate within the water column, which aids in their retention within the estuary. 相似文献
70.
Christof Müller 《Marine Geophysical Researches》2005,26(2-4):197-206
Between 1997 and 1999 several marine seismic surveys were carried out in Kiel Bay aimed towards the development of a three-dimensional
acquisition and interpretation technique for small scale subsurface structures using high-frequency sources and multichannel
streamers. The data set was recently revisited by the author and reprocessed to obtain a multichannel stacked seismic data
cube. Nominal hydrophone positions are deduced by determining offsets from first arrival times and estimating the hydrophone
positions under consideration of the ships track. Processing towards a ‘seismic cube’ mainly comprised CMP sorting, constant
velocity NMO correction and stacking. The resulting VHR 3-D seismic ‘brute stack cube’ reveals rich structural details. The
fluvial Pleistocene channel system already documented in an earlier publication was tracked further to the north. It is situated
below a flat cover of gas-bearing Holocene sediments, which locally constitute the seafloor. This till-horizon is superimposed
on a second till layer showing strong topographic variations. Seismic signal phase and shielding effects indicate the possible
presence of gas in these formations. This case history demonstrates that the VHR 3-D seismic method is a feasible tool for
low budget investigation and research. 相似文献